Product ID:FYRQUEL 220
MSDS Date:12/08/1999
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKSXX

Emergency Phone: 914-693-6946

Info Phone: 800-666-1200

Preparer: PROD SAFETY;914-674-5000

Cage: UO018

Telephone: 800-666-1200

Cage: UO018

TRIPHENYL PHOSPHATE

CAS: 115-86-6

RTECS: TC8400000

OSHA PEL 3 MG/M3

ACGIH TLV: 3 MG/M3

BUTYLATED TRIPHENYL PHOSPHATE MIXTURE

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: INHALATION OF VAPORS OR
MISTS MAY CAUSE RESP TRACT IRRITATION. TRIPHENYL PHOSPHATE MAY
CAUSE CHOLINESTERASE INHIBITION. SKIN: CONTACT MAY CAUSE MILD
IRRIT. EYE: CONTACT MAY CAUSE MILD IR RIT. INGESTION: MAY CAUSE
IRRIT OF GASTROINTESTINAL SYSTEM & DIARRHEA. INGESTION OF
TRIPHENYL PHOSPHATE MAY CAUSE CHOLINESTERASE INHIBITION. OTHER
PREC: EMPTIED CNTNR MAY RETAIN PROD RESIDUE. FOLLOW ALL WARNINGS &
PREC EVEN AFTER CNTNR IS EMPTY. STORAGE: STORE AWAY FROM FOOD &
ANIMAL FEED. CNTNRS SHLD BE STORED IN A COOL DRY WELL VENTILATED
AREA AWAY FROM FLAMM/OXIDIZING MATL & SOURCES OF HEAT/F LAME.
EXERCISE CAUTION TO (SIGNS/SYMPS)
Explanation of Carcinogenicity:PROD WAS EXAMINED FOR MUTAGENICITY &
CLASTOGENIC ACTIVITY IN SERIES OF IN VITRO ASSAYS. NO EVIDENCE OF
GENETIC ACTIVITY WAS NOTED IN ANY OF THESE ASSAYS. PROD WAS TESTED
IN AN IN VITRO MALIGNANT TRAN SFORMATION ASSAY USING BALB/3T3
CELLS. IT DID NOT INDUCE MORPHOLOGICAL TRANSFORMATIONS & THUS DID
NOT EXHIBIT CARCINOGENIC POTENTIAL IN THIS ASSAY.
Effects of Overexposure:ACUTE/CHRONIC: PREVENT DMG TO OR LEAK FROM
CNTNR. PRLNG STORAGE @ ELEVATED TEMP UNDER WET ALKALINE/ACIDIC
CONDITIONS SHLD BE AVOIDED TO ASSURE PROD INTEGRITY. CARE SHLD BE
TAKEN TO PREVENT MOISTURE C ONDENSATION IN THE CNTNR. CARBON STEEL
IS THE PREFERRED MATL OF CONSTRUCTION FOR STORAGE CNTNR. THE PROD
IS NORMALLY SHIPPED IN UNLINED TANK CARS, TRUCKS AND DRUMS. MAXIMUM
STORAGE TEMP: 150.80F (66.0 C). HIGHER IN ABSENCE AIR/MOISTURE.
GENERAL COMMENT: AT TEMP <4.4C (40F), VISCOSITY CHARACTERISTICS ARE
SUCH THAT IMPROVED PUMPING RATES MAY BE ACHIEVED BY WARMING. THE
PROD CAN BE STORED & TRANSPORTE D IN EQUIP CONSTRUCTED OF MILD
STEEL.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
NEUROMUSCULAR DISORDERS MAY BE AT AN INCREASED RISK FROM EXPOSURE
TO THIS MATERIAL.

First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING,
GIVE ARTIF RESPI. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MED
ATTN. SKIN: REMOVE CONTAM CLOTHES & EQUIP. THOROUGHLY WASH ALL
AFFECTED AREA S W/SOAP & PLENTY OF WATER. GET MED ATTN IF IRRIT
PERSISTS. WASH CONTAM CLOTHES BEFORE REUSE. THOROUGHLY
CLEAN/DESTROY CONTAM SHOES. EYE: IMMED FLUSH W/PLENTY OF RUNNING
WATER FOR AT LEAST 15 MIN. IF VICTIM IS WEARING CONTACT LENSES,
REMOVE THEM. HOLD EYELIDS APART DURING FLUSHING TO ENSURE RINSING
OF ENTIRE SURFACE OF EYE & LIDS W/WATER. GET MED ATTN IF IRRIT
PERSISTS. INGEST: GET MED ATTN (SUP DATA)

Flash Point Method:PMCC
Flash Point:=246.1C, 475.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:USE WATER FOG/SPRAY, DRY CHEMICAL, FOAM OR CARBON
DIOXIDE. FIREFIGHT: EXCESS HEAT. HI PRESS H*2O MAY SPREAD PROD FROM
CNTNR INCR CONTAM/FIRE HAZ. DIKE H*2O. DON'T ALLOW TO WATERWAY.
Fire Fighting Procedures:PREVENT HUMAN EXPOS TO FIRE, SMOKE, FUMES OR
PROD OF COMBUSTION. EVACUATE NON-ESSENTIAL PERSON. FIREFIGHTERS
WEAR NIOSH APPRVD FULL-FACE SCBA & IMPERVIOUS PROTECTIVE CLOTHES.
IF POSS, MOVE CNTNRS FROM FIRE AREA. IF NOT LEAKING, KEEP FIRE
EXPOSED CNTNR COOL W/WATER FOG/SPRAY TO PREVENT RUPTURE DUE TO (SEE
EXTING MEDIA).
Unusual Fire/Explosion Hazard:PROD IS NOT DEFINED AS FLAMM/COMBUST. IT
IS SELF-EXTINGUISHING ONCE SOURCE OF IGNIT IS RMVD. MATL IS NOT
SENSITIVE TO STATIC DISCHARGE/ PHYSICAL IMPACT. IT MAY DECOMPOSE
UNDER FIRE CONDS. DECOMP OF P ROD UNDER FIRE CONDS CAN PROD CO,
PHOSPHORUS OXIDES, & ORGANIC DECOMP PRODS. NO OTHER FIRE/EXPLOS HAZ
OF PROD ARE KNOWN.

Spill Release Procedures:ISOLATE SPILL AREA & RESTRICT NONESSENTIAL
PERSONS. ALL PERSONS INVOLVED IN SPILL CLEANUP SHOULD FOLLOW APPROP
IH PRACTICES. STOP SOURCE OF SPILL IF POSS W/O BEING INJURED. DIKE
AREA TO PREVENT SPILL FROM SPREADING. SOAK UP LIQ W/SUITABLE
ABSORBENT SUCH AS CLAY, SAWDUST, KITTY LITTER. SWEEP UP ABSORBED
MATL & PLACE IN CHEM WASTE CNTNR FOR DISPOSAL. CAUTION! SPILL AREA
MAY BE SLIPPERY.(OTHER INFO)

Handling and Storage Precautions:WEAR PROT CLOTHES INCL CHEM GOGGS &
RUBBER GLOVES TO AVOID EYE & SKIN CONTACT. HANDLE IN A WELL
VENTILATED AREA. AVOID INHAL OF VAPOR/MIST. WASH THOROUGHLY AFTER
HANDLING. CNTNRS SHLD BE LOCATED IN A REA WHERE THEY CAN BE
ROTATED REGULARLY (FIRST IN, FIRST OUT) & VISUALLY INSPECTED FOR
(OTHER PREC)
Other Precautions:HAND/STORAGE: DENTS & BULGING ON A WEEKLY BASIS. IF
BULGED DRUMS ARE FOUND, THEY SHLD BE VENTED IN AN OPEN AREA BY
REMOVING THE TWO INCH BUNG VERY SLOWLY. THE TWO INCH SHLD NOT BE
REMOVED COMPLETELY U NTIL THERE IS NO SOUND OF PRESSURE BEING
RELEASED. THE BUNG CAN THEN BE REMOVED, BUT SLOWLY & WITH C ARE.
(ACUTE/CHRONIC)

Respiratory Protection:USE A NIOSH APPRVD ORGANIC VAP/ACID GAS RESP
(OVAG) W/DUST, MIST & FUME FILTERS TO REDUCE POTENTIAL FOR INHAL
EXPOS IF USE CONDITIONS GENERATE VAP, MIST, OR AEROSOL & ADEQ VENT
(OUTDOOR/WELL-VENTED AR EA) IS NOT AVAIL. WHEN EXPOS POTENTIAL
NECESSITATES A HIGHER LEVEL OF PROT, USE A NIOSH-APPROVED
POSS-PRESS, PRESS DEMAND, AIR-SUPPPLIED RESP. (SEE OTHER INFO)
Ventilation:AT ELEV PROCESSING TEMP OR IF COND GENERATE AIRBORNE VAP,
AEROSOL, MIST, MATL SHLD BE HANDLED IN WELL VENTED AREA. WHERE NOT
AVAIL, RESP PROT SHOLD BE USED.
Protective Gloves:COMBINATION NEOPRENE OVER NATURAL LATEX GLOVES
RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:SAFETY SHOWERS, W/QUICK OPENING VALVES WHICH
STAY OPEN & EYEWASH FOUNTAIN, OR OTHER MEANS OF WASHING EYES
W/GENTLE FLOW OF COOL TO TEPID TAP WATER, SHLD BE READILY AVAIL
WHERE MATL IS (WORK HYGIENE)
Work Hygienic Practices:OTHER PROT EQUIP: HANDLED/STORED. WATER SHLD BE
SUPPLIED THRU INSULATED & HEAT-TRACED LINES TO PREVENT FREEZE-UPS
IN COLD WEATHER. LONG SLEEVE CLOTHES MAY BE USED TO MINIMIZE SKIN
CONTACT. (SUP DAT)
Supplemental Safety and Health
FIRST AID: BY CALLING A MD OR POISON CONTROL CENTER IMMED. DO NOT
INDUCE VOMIT UNLESS DIRECTED TO DO SO BY MED PERSONNEL. IF VOMIT
OCCURS, KEEP HEAD BELOW HIPS TO REDUCE RISK OF ASPIRATION. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. WORK HYG: PREVENT
CONT W/LIQ/AEROSOL USING PROT CLOTHES, GLOVES, FOOTWEAR.

Boiling Pt:B.P. Text:N/D
Melt/Freeze Pt:M.P/F.P Text:N/D
Vapor Pres:0.1 MM HG @ 37.8C (100F)
Vapor Density:N/D
Spec Gravity:N/D
pH:N/D
Viscosity:@ 38C (100F) = 220 SUS
Evaporation Rate & Reference:N/D
Solubility in Water:0.1 G/100 ML
Appearance and Odor:CLEAR, YELLOW LIQUID; ESSENTIALLY ODORLESS.
Percent Volatiles by Volume:N/D

Stability Indicator/Materials to Avoid:YES
THIS PRODUCT IS INCOMPATIBLE WITH STRONG OXIDIZERS, STRONG ACIDS AND
STRONG ALKALIS. IT HYDROLYZES SLOWLY AT AMBIENT TEMPERATURES IN
ACIDIC OR ALKALINE AQUEOUS SOLUTIONS. AVOID CONTACT WITH STRONG
ACIDS, STRONG BASES AND S
Stability Condition to Avoid:PROD IS STABLE @ AMBIENT TEMP & ATMOS
PRESS. IT IS NOT SELF-REACTIVE & IS NOT SENSITIVE TO STATIC
DISCHARGE/PHYS IMPACT. PRLNGD STOR @ ELEVATED TEMP (> 65.6C/15OF)
SHOULD BE AVOIDED.
Hazardous Decomposition Products:UNDER WET ACIDIC/ALKALINE CONDITIONS,
PROD HYDROLYZES SLOWLY & NONVIOLENTLY TO FORM PHENOL, SUBSTITUTED
PHENOLS, & ARYL PHOSPHORIC ACIDS. VAPS MAY DECOMPOSE AT ELEVATED
TEMPS TO RELEASE HARMFUL MATL.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION IS NOT
EXPECTED TO OCCUR.

Waste Disposal Methods:MATL THAT CANNOT BE USED/CHEMICALLY REPROCESSED
SHLD BE DISPOSED OF IAW ALL APPLIC FEDERAL, STATE & LOCAL REGS.
PROD CNTNRS DESIGNED FOR SINGLE USE SHOULD BE THOROUGHLY EMPTIED
BEFORE DISPOSAL. NOTE: ST & LOC REGS MAY BE MORE STRINGENT THAN
FED. EMPTIED CNTNRS MAY RETAIN RESIDUE OF MATL. FOLLOW ALL
WARNINGS & PREC EVEN AFTER CNTNR (SEE SARA REG)

Toxicological Information:INHAL: ACUTE INHAL LC50 (RAT) FOR MATL
FOLLOWING 4-HR EXPOS WAS >3.1 MG/L, THE HIGHEST ATTAINABLE CONC. NO
EFFECTS WERE OBSERVED @ THIS LEVEL. CHRONIC INHAL EXPOS EFFECTS FOR
THIS PROD NOT KNOWN. DERM AL: PRACTICALLY NON-TOXIC; ACUTE DERMAL
LD50 (RABBIT) > 2000 MG/KG. THIS MATL WAS FOUND TO BE A MILD SKIN
IRRIT IN RABBITS FOLLOWING A 24 HR EXPOS. CHRONIC DERMAL EXPOS
EFFECTS FOR THIS PROD ARE NOT K NOWN. HOWEVER, PRLNG/RPTD CNTCT MAY
CAUSE IRRIT. EYE: MILD IRRIT TO RABBIT EYES. INGEST: PRACTICALLY
NON-TOXIC; ACUTE ORAL LD50 (RAT) > 5000 MG/KG. (SEE FED REGS)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS PROD CONTAINS TRIPHENYL PHOSPHATE WHICH IS A MARINE
POLLUTANT PER 49CFR172.101, APPENDIX B. ECOTOXICOLOGICAL INFO:
96-HR LC50 (RAINBOW TROUT) = 2 MG/L. 96 HR LC50 (SHEEPSHEAD NINNOW)
= > 1 MG/L. 96 HR LC50 (MYSID SHRIMP) - 0.39 MG/L; DISTRIBUTION:
TRIARYL PHOSPHATE ESTERS, INCLUDING TRIPHENYL PHOSPHATE, EXHIBIT
LOW AQUEOUS SOLUBILITY, HAVE MODERATE POTENTIAL FOR
BIOCONCENTRATION & READILY UND ERGO BIODEGRADATION; CHEMICAL FATE:
THIS MATERIAL IS READILY BIODEGRADABLE. HYDROLYSIS RATES FOR
TRIPHENYL PHOSPHATE, A CHEMICAL COMPONENT, ARE: @ PH 9.5:
HALF-LIFE: 0.23 DAYS. AT PH 8.3: HALF-LIFE: 7 .5 DAYS.

Transport Information:SHIPMENTS NOT REGULATED FOR TRANSPORT: SURFACE
TRANSPORT W/N NORTH AMERICA (USA, MEXICO, CANADA) IN PKGS OF 119
GAL OR LESS (NON BULK). AIR TRANSPORT W/N NORTH AMER. SHIPMENTS
REGULATED FOR TRANSPORT: BULK SURFACE SHIPMENTS W/N NORTH AMER.
EXPORT SHIPMENTS (EXCLUDE NON BULK SHIPMENTS TO MEXICO & CANADA &
SHIPMENTS VIA AIR TRANSPORT TO CANADA & MEXICO). ENVIRONMENTALLY
HAZ SUBSTANCE, LIQ, N.O.S. (T RIPHENYL PHOSPHATE/TERT-BUTYLATED
TRIPHENYL PHOSPHATES MIXTURES CONTAINING 10%- 48% TRIPHENYL
PHOSPHATES) 9, UN3082, PG III. NORTH AMER EMER RESP GUIDE NO. 171.
REQD LABELS: PRIMARY LABEL: CLASS 9. SU BSIDIARY RISK LABEL: MARINE
POLLUTANT.

SARA Title III Information:N/P. WASTE DISPOSAL: IS EMPTIED. THIS
PRODUCT, IF UNUSED, DOES NOT MEET THE EPA'S RCRA CRITERIA AS EITHER
A LISTED OR A CHARACTERISTIC HAZARDOUS WASTE. GENERATORS OF WASTES
ARE REQUIRED TO EVALUATE T HEIR MATERIALS FOR COMPLIANCE WITH
RCRAAND LOCAL, STATE AND FEDERAL DISPOSAL PROCEDURES AND
REGULATIONS. CONTAINERS SHOULD BE DRAINED OF RESIDUAL MATERIAL
BEFORE DISPOSAL. EMPTIED CONTAINERS SHOULD BE DISPOSED OF IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND FEDERAL LAWS &
REGULATIONS.
Federal Regulatory Information:TOXICOLOGICAL INFO: CHRONIC INGESTION:
DAILY INGEST BY RATS OF 100,400,1600 PPM OF THIS MATL IN DIET FOR 3
MO. PRODUCED INCR LIVER & ADRENAL GLAND WTS IN FEMALE & INCR LIVER
WT OF MALES @ HI DOSE LEVE L. NO HISTOPATHOLOGICAL CHANGES WERE
NOTED. REPROD EFFECTS: DAILY ADMIN OF MAT @ 100,400,100 MG/KG TO
RATS ON DAY 6-20 OF GESTATION SHOWED MATERNAL TOXICITY &
FETO-TOXICITY (REDUCTION IN FETAL BODY WT @ HI DOSES) BUT NO
INDICATION OF TERATOGENICITY WERE OBSERVED. TARGET ORGANS:
OVEREXPOSURE TO THIS PRODUCT MAY AFFECT THE SKIN, EYES,
RESPIRATORY SYSTEM, & CENTRAL AND PERIPHERAL NERVOUS SYSTEM.
State Regulatory Information:COMPONENT TRIPHENYL PHOSPHATE IS SUBJECT
TO THE FOLLOWING: ENVIROMENTAL LISTS: DSL: DOMESTIC SUBSTANCE LIST
- CANADA; MA. LIST: MASSACHUSETTS SUBSTANCE LIST; NJ R-T-K: NEW
JERSEY R-T-K HAZARD. SUB; PA . LIST: PENN HAZARDOUS SUBSTANCE LIST;
TSCA: TOXIC SUBST. CON. ACT - LISTED. COMPONENT BUTYLATED TRIPHENYL
PHOSPHATE MIXTURE IS SUBJECT TO THE FOLLOWING: DSL: DOMESTIC
SUBSTANCE LIST - CANADA; TSCA: T OXIC SUBST. CONT. ACT - LISTED. NO
OTHER REGULATORY INFO IS AVAIL ON THIS PROD. WHMIS HAZARD CLASS:
NOT CONTROLLED.